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1 article(s) from Schleife, Frederik

Probing the magnetic superexchange couplings between terminal Cu^II ions in heterotrinuclear bis(oxamidato) type complexes

Mohammad A. Abdulmalic,
Saddam Weheabby,
Francois E. Meva,
Azar Aliabadi,
Vladislav Kataev,
Bernd Büchner,
Frederik Schleife,
Berthold Kersting and
Tobias Rüffer

Beilstein J. Nanotechnol. 2017, 8, 789–800, doi:10.3762/bjnano.8.82

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Figure 1: Chemical structures of type I–IV complexes.

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Figure 2: Expected J couplings between the central and terminal paramagnetic metal ions in type III/IV comple...

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Scheme 1: Synthesis of the heterotrinuclear Cu^IINi^IICu^II type IV complexes 1–3.

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Figure 3: ORTEP diagrams (50% ellipsoid probability) of the molecular structures of 1A (top), 2A (middle) and ...

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Figure 4: Magnetization versus magnetic field M(H) of 1 at T = 1.8 K (symbols) together with the fit of M(H) ...

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Figure 5: Magnetization versus magnetic field M(H) of 2 at T = 1.8 K (symbols) together with the fit of M(H) ...

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Figure 6: Magnetization versus magnetic field M(H) of 3 at T = 1.8 K (symbols) together with the fit of M(H) ...

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Figure 7: Temperature dependence of the magnetic susceptibility χ = M/H and of the corresponding inverse susc...

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Figure 8: Temperature dependence of the magnetic susceptibility χ = M/H and of the corresponding inverse susc...

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Figure 9: Temperature dependence of the magnetic susceptibility χ = M/H and of the corresponding inverse susc...

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Figure 10: Main panel: Difference between the calculated and measured static susceptibility for 3. Inset: Temp...

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Published 06 Apr 2017

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Probing the magnetic superexchange couplings between terminal CuII ions in heterotrinuclear bis(oxamidato) type complexes

Probing the magnetic superexchange couplings between terminal Cu^II ions in heterotrinuclear bis(oxamidato) type complexes